Journal
TETRAHEDRON
Volume 70, Issue 8, Pages 1646-1650Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.01.018
Keywords
Hydrogen bond; Organocatalysis; Ring-opening; Epoxide; Ionic catalyst
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Funding
- University of Bordeaux 1
- French Ministry of Research
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Supramolecular ionic organocatalysts and a metal-based catalyst were investigated in the ring-opening of epoxides by amines, without any artifice to enhance conversion (i.e., solvophobic effect, extended reaction time, heating, excess of amine, high catalyst loading). Different beta-amino-alcohols were obtained in satisfying conversion (50-80%) in 24 h, under mild conditions. (C) 2014 Elsevier Ltd. All rights reserved.
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