Journal
TETRAHEDRON
Volume 70, Issue 46, Pages 8872-8878Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.09.091
Keywords
Trifluoromethylthiolation; Trifluoromethylselenolation; Copper; Propargylic trifluoromethyl selenoethers; Allylic trifluoromethyl selenoethers
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Funding
- National Natural Science Foundation of China [21072030, 21372044]
- Research Fund for the Doctoral Program of Higher Education of China [20123514110003]
- SRF for ROCS, SEM, China [2012-1707]
- Science Foundation of the Fujian Province, China [2013J101040]
- Fuzhou University [022318, 022494]
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The copper-mediated trifluoromethylselenolation of propargylic chlorides and allylic bromides is described. This approach provides a wide range of propargylic and allylic trifluoromethyl selenoethers in moderate to good yields. These results open the way to synthesis strategies for various trifluoromethylselenolated compounds. (C) 2014 Elsevier Ltd. All rights reserved.
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