Journal
TETRAHEDRON
Volume 69, Issue 27-28, Pages 5751-5757Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.04.029
Keywords
Gold; Cross-coupling; Oxidation; Arenes
Categories
Funding
- Swiss National Science Foundation
- European Research Council (ERC) [307948]
- Organic Chemistry Institute of the University of Zurich
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The reactivity of electron-deficient arene gold(III) complexes toward nucleophilic aromatic and heteraromatic counterparts has been studied. 1-Methylindole proved to be the best reaction partner while trimethoxybenzenes did not react. The ancillary ligand on gold also influenced the reactivity in the order PPh3>(PBu3)-Bu-t>IPr. An oxidative cross-coupling starting from the corresponding gold(I) complexes in presence of hypervalent iodide oxidants was also studied. (C) 2013 Elsevier Ltd. All rights reserved.
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