Journal
TETRAHEDRON
Volume 69, Issue 30, Pages 6046-6050Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.05.073
Keywords
Trifluoromethylthiolation; Benzyl bromides; Copper reagent
Categories
Funding
- National Natural Science Foundation of China [21072030]
- Fuzhou University [022318]
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The nudeophilic trifluoromethylthiolation of benzyl bromides using (bpy)Cu(SCF3) gave the desired products of benzyl trifluoromethyl sulfides in good to excellent yields. A diverse set of important functional groups including cyano, nitro, ester, alkoxy, halide, and heterocyclic groups can be well tolerated in the protocol. (C) 2013 Elsevier Ltd. All rights reserved.
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