Journal
TETRAHEDRON
Volume 69, Issue 40, Pages 8572-8578Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.07.082
Keywords
Flavin; Dendrimer; Diimide; Reduction; Olefin
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [25620086, 24105517, 24550156, 25620059] Funding Source: KAKEN
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A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure. (C) 2013 Elsevier Ltd. All rights reserved.
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