Journal
TETRAHEDRON
Volume 69, Issue 46, Pages 9761-9765Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.09.010
Keywords
Palladium; Diazonium salts; Cross-coupling reactions; Aqueous medium
Categories
Funding
- MICINN of Spain [CTQ2011-23121]
- Generalitat de Catalunya [2009SGR637]
- University of Girona
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Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)(2) as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts. (C) 2013 Elsevier Ltd. All rights reserved.
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