Journal
TETRAHEDRON
Volume 69, Issue 35, Pages 7253-7257Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.06.081
Keywords
Asymmetric-axle-supported; Hydrosilylation; Ketimines; Trichlorosilane
Categories
Funding
- 973 Program [2009CB 522300]
- Hebei University
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A novel asymmetric-axle-supported chiral N-O amide was synthesized and used in catalytic enantioselective hydrosilylation of N-aryl ketimines with HSiCl3 at room temperature instead of the typical -20 degrees C. High conversion yield and high enantioselectivity up to 96% were observed. (C) 2013 The Authors. Published by Elsevier Ltd. All rights reserved.
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