Journal
TETRAHEDRON
Volume 69, Issue 26, Pages 5312-5318Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.04.130
Keywords
Organosilica; Alkoxysilane; Molecular building block; Cross-coupling; Sol-gel polymerization
Categories
Funding
- Grants-in-Aid for Scientific Research [24107002] Funding Source: KAKEN
Ask authors/readers for more resources
We report an efficient synthetic approach for well-designed organic-bridged alkoxysilanes, which allow the formation of highly functional organosilica hybrids under mild sol gel conditions. A series of molecular building blocks containing a triisopropoxysilyl group were synthesized and used in cross-coupling reactions. The triisopropoxysilyl group showed a good tolerance for various organic transformations. 1,4-Diketo-3,6-dithienylpyrrolo[3,4-c]pyrrole-bridged triisopropoxysilane was successfully prepared, allowing rapid formation of organosilica hybrid without loss of functionality under mildly acidic conditions. (C) 2013 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available