Journal
TETRAHEDRON
Volume 69, Issue 20, Pages 4076-4080Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.03.065
Keywords
Vicinal tricarbonyl; gem-Diol; Hemiketal; Reversibility
Categories
Funding
- Japan Society for the Promotion of Science (JSPS) and Japan [21350068]
- JSR Corporation
- Grants-in-Aid for Scientific Research [25288060, 21350068] Funding Source: KAKEN
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We have synthesized and fully characterized an acyclic bifunctional vicinal tricarbonyl compound, its hydrate, and its ethanol-adduct, which could be converted to one another by utilizing the reversible addition-elimination of water or ethanol. X-ray single crystal study revealed that the bistriketone expanded and contracted by 10-30% in length during the interconversion. (C) 2013 Elsevier Ltd. All rights reserved.
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