Journal
TETRAHEDRON
Volume 69, Issue 1, Pages 57-68Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.10.069
Keywords
Macrocycles; Bis-oxazolines; Oxidative Heck; CuAAC click; Cadiot-Chodkiewicz; Rotaxane
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Funding
- EPSRC [EP/G006695/1]
- EPSRC [EP/G006695/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G006695/1] Funding Source: researchfish
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A C-1-symmetric Box macrocycle has been synthesized for the first time. The Box macrocycle along with other C-1 and C-2-symmetric Box ligands were evaluated and compared as ligands in the Cadiot-Chodkiewicz, oxidative Heck and CuAAC 'click' reactions as part of our studies towards achieving active-metal template synthesis of mechanically planar chiral rotaxanes. This study constitutes the first report of Cadiot-Chodkiewicz and CuAAC 'click' reactions using Box ligands, as well as the first dedicated study of oxidative Heck reactions using Box ligands. (C) 2012 Elsevier Ltd. All rights reserved.
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