Journal
TETRAHEDRON
Volume 68, Issue 11, Pages 2527-2531Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.12.085
Keywords
Copper catalyst; Terminal alkyne; Trifluoromethylation reaction
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Funding
- King Abdullah University of Science and Technology
- National Natural Science Foundation of China [21072030]
- Fuzhou University [022318]
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A catalytic process for trifluoromethylation of terminal alkynes with Togni's reagent has been developed, affording trifluoromethylated acetylenes in good to excellent yields. The reaction is conducted at room temperature and exhibits tolerance to a range of functional groups. (C) 2012 Elsevier Ltd. All rights reserved.
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