Journal
TETRAHEDRON
Volume 68, Issue 34, Pages 6856-6861Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.06.028
Keywords
Iodoperfluoroalkylation; Addition-elimination reaction; Electron-deficient olefin; Photoinduced radical reaction
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Funding
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [24550247] Funding Source: KAKEN
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Photoinduced radical perfluoroalkylation of various simple electron-deficient olefins was achieved in the presence of an aqueous Na2S2O3 solution. The reactions proceeded smoothly to give addition or addition elimination products. The ability of the products to be used as radical precursors or Michael acceptors was also demonstrated. (C) 2012 Elsevier Ltd. All rights reserved.
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