4.4 Article

Photoinduced addition and addition-elimination reactions of perfluoroalkyl iodides to electron-deficient olefins

Journal

TETRAHEDRON
Volume 68, Issue 34, Pages 6856-6861

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.06.028

Keywords

Iodoperfluoroalkylation; Addition-elimination reaction; Electron-deficient olefin; Photoinduced radical reaction

Funding

  1. Asahi Glass Foundation
  2. Grants-in-Aid for Scientific Research [24550247] Funding Source: KAKEN

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Photoinduced radical perfluoroalkylation of various simple electron-deficient olefins was achieved in the presence of an aqueous Na2S2O3 solution. The reactions proceeded smoothly to give addition or addition elimination products. The ability of the products to be used as radical precursors or Michael acceptors was also demonstrated. (C) 2012 Elsevier Ltd. All rights reserved.

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