Journal
TETRAHEDRON
Volume 68, Issue 50, Pages 10333-10337Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.09.110
Keywords
Iron catalysis; Organic peroxides; Peroxidation; Carbonylation; Alkene di-functionalization
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Funding
- National Science Foundation of China [20832002, 21072223, 21272267]
- State Key Laboratory of Heavy Oil Processing [2012-1-06]
- Fundamental Research Funds for the Central Universities
- Renmin University of China [10XNL017]
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A general and practical method for the synthesis of alpha-ester-beta-keto peroxides has been achieved by iron-catalyzed three-component reactions of alkenes, aldehydes, and TBHP. A wide variety of functionalized organic peroxides were synthesized efficiently and selectively. (C) 2012 Elsevier Ltd. All rights reserved.
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