Journal
TETRAHEDRON
Volume 68, Issue 45, Pages 9289-9292Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.08.035
Keywords
Aldol reaction; Wittig olifination; Cyclization; Salinipyrones; Pacificanones
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Funding
- CSIR-UGC, New Delhi, India
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A synthetic approach for the total synthesis of salinipyrone A has been developed. Key steps involve the TiCl4-mediated vinylogous Mukaiyama aldol reaction (VMAR) of chiral ketene silyl N,O-acetal with propionaldyhyde, an aldol condensation, Witting olefination, and a cyclization. The synthesis proceeds in eight steps. (C) 2012 Elsevier Ltd. All rights reserved.
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