Journal
TETRAHEDRON
Volume 68, Issue 26, Pages 5157-5161Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.04.005
Keywords
Nickel; Catalysis; Amination; C-O bond activation; Heteroarene
Categories
Funding
- MEXT, Japan
- Grants-in-Aid for Scientific Research [23685021, 22245016] Funding Source: KAKEN
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Ni(0)/NHC-based catalyst system can promote the amination of N-heteroaryl methyl ethers via the cleavage of normally unreactive carbon oxygen bonds. Electron-deficient N-heteroarenes including pyridine, quinoline, isoquinoline, and quinoxaline undergo amination to afford aminopyridine and related heteroarenes, which constitute an important class of compounds. (C)2012 Elsevier Ltd. All rights reserved.
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