Journal
TETRAHEDRON
Volume 68, Issue 48, Pages 9949-9953Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.09.083
Keywords
Copper catalyst; Electrophilic trifluoromethylation reaction; Trifluoromethylarenes
Categories
Funding
- National Natural Science Foundation of China [21072030]
- Fuzhou University [022318]
- King Abdullah University of Science and Technology
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An efficient room temperature copper-catalyzed trifluoromethylation of organotrifluoroborates under the base free condition using an electrophilic trifluoromethylating reagent is demonstrated. The corresponding trifluoromethylarenes were obtained in good to excellent yields and the reaction tolerates a wide range of functional groups. (C) 2012 Elsevier Ltd. All rights reserved.
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