Journal
TETRAHEDRON
Volume 68, Issue 38, Pages 7949-7955Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.07.009
Keywords
Coinage metal; N-Heterocyclic carbene; Gold; Silver; Copper
Categories
Funding
- National Natural Science Foundation of China [20902028, 21172077]
- Program for New Century Excellent Talents in University [NCET-10-0403]
- Guangdong Natural Science Foundation [9451064101002851, 10351064101000000]
- National Basic Research Program of China (973) [2011CB808600]
- Fundamental Research Funds for the Central Universities, SCUT [2012ZZ0038]
- opening Foundation of Zhejiang Provincial Top Key Discipline
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A novel direct and practical synthetic route leading to N-heterocyclic carbene coinage metal complexes has been developed by using air stable, commercial available Au(III) salt [MAuCl4 center dot 2H(2)O], CuCln (n=1,2) or AgCl, and imidazolium salts as starting materials. The reaction proceeded without sacrificing carbene transfer agent (Ag2O) or using highly sensitive free NHC. (C) 2012 Elsevier Ltd. All rights reserved.
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