Journal
TETRAHEDRON
Volume 67, Issue 52, Pages 10179-10185Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.09.011
Keywords
Total synthesis; Norcembranolides; 10-Epigyrosanolide E; Samarium iodide; Beta-alkoxyvinyl sulfoxides; Ring-closing olefin metathesis
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Funding
- Marine Biotechnology Program
- Ministry of Land, Transport and Maritime Affairs, Republic of Korea
- Centre for Bioactive Molecular Hybrids (Yonsei University and KOSEF)
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Total synthesis of (+)-10-epigyrosanolide E was accomplished employing SmI2-mediated 5-exo cyclization of an aldehydo beta-alkoxyvinyl sulfoxide and ring-closing metathesis reaction. (C) 2011 Elsevier Ltd. All rights reserved.
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