Journal
TETRAHEDRON
Volume 67, Issue 45, Pages 8659-8664Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.09.046
Keywords
Fluorous compounds; Matsuda-Heck; Arenediazonium salt; Palladium; Palladacycle; Nanoparticles
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Funding
- MICINN of Spain [CTQ2007-62771/BQU, CTQ2008-05409, CTQ2010-20387, CSD2007-00006]
- DURSI-Generalitat de Catalunya [2009SGR-1441, 2009SGR-637]
- Universitat Autonoma de Barcelona
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Fluorous aryl compounds are obtained through the arylation of different electron-rich and electron-poor olefins with an arenediazonium salt bearing a fully fluorinated octyl-ponytail at the para position. The Matsuda-Heck reactions are catalyzed by Pd(OAc)(2) or 4-hydroxyacetophenone oxime-derived palladacycle as efficient sources of Pd nanoparticles, with loadings of 1 mol % Pd, at room temperature, in methanol and without the need to add external base. (C) 2011 Elsevier Ltd. All rights reserved.
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