Journal
TETRAHEDRON
Volume 67, Issue 11, Pages 2090-2095Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.01.054
Keywords
Imines; Oxaziridines; Azodioxy; Oximes; C-Nitroso compounds
Categories
Funding
- University of Salento
- C.I.N.M.P.I.S. (Consorzio Interuniversitario Nazionale Metodologie e Processi Innovativi di Sintesi)
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This article reports a simple and efficient synthesis of C-nitroso compounds (azodioxy esters or ketones and oximes) through a double oxidation of cyclic imines (4,5-dihydrooxazoles and 3,4-dihydro-2H-pyrroles) with m-CPBA. C-Nitroso derivatives seem to be potential donors of nitric oxide, one of the most powerful biological messenger. Published by Elsevier Ltd.
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