4.4 Article

Synthesis of lipophilic bisanthracene fluorophores: versatile building blocks toward the synthesis of new light-harvesting dendrimers

Journal

TETRAHEDRON
Volume 67, Issue 49, Pages 9484-9490

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.10.021

Keywords

Bisanthracene; Fluorophore; Suzuki-Miyaura cross-coupling reaction; Light-harvesting dendrimer; Energy transfer

Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan
  2. Grants-in-Aid for Scientific Research [22550032] Funding Source: KAKEN

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Lipophilic bisanthracene-based fluorophore and its derivatives were synthesized by the Suzuki-Miyaura cross-coupling reaction of 9-anthrylboronic acid with a substituted dibromobenzene. In addition to desirable fluorescent properties, these molecular systems were demonstrated to serve as versatile building blocks toward the synthesis of two types of new light-harvesting dendrimers due to their chemical stability. (C) 2011 Elsevier Ltd. All rights reserved.

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