Journal
TETRAHEDRON
Volume 67, Issue 52, Pages 10186-10194Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.08.070
Keywords
Bifinctional; Biscinchona alkaloids; Nitroalkenes; Conjugate addition; Baclofen
Categories
Funding
- Major State Basic Research Development Program [2010CB833302]
- Shanghai Municipal Committee of Science and Technology [09JC1417300]
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The novel bifunctional bisalkaloids have been developed as highly efficient catalysts for the asymmetric conjugate addition of 1,3-dicarbonyl compounds to nitroalkenes with low catalyst loading (1 mol %) at ambient temperature, providing the products with excellent enantioselectivities (up to 97% ee). Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.
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