Journal
TETRAHEDRON
Volume 66, Issue 13, Pages 2439-2443Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.01.085
Keywords
Enantioselective organocatalysis; Intramolecular Morita-Baylis-Hillman reaction; Chiral phosphinothiourea; Amino acids; Enones
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Funding
- National Natural Science Foundation of China [20772029]
- Program for New Century Excellent Talents in University [NCET-07-0286]
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A series of chiral bifunctional phosphinothioureas derived from L-amino acids have been developed to promote the enantioselective intramolecular Morita-Baylis-Hillman reaction. The process afforded the cyclic hydroxyl enones with up to 84% ee and good yields under mild conditions. (C) 2010 Elsevier Ltd. All rights reserved.
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