Journal
TETRAHEDRON
Volume 66, Issue 38, Pages 7605-7611Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.07.038
Keywords
o-Quinone; Tetrathiafulvalene; Tetrathiooxalate; Acceptor-donor-acceptor triad
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Funding
- Russian Foundation for Basic Research [10-03-00788-a, 09-03-97034-r_povolzh'e_a]
- Program for support of Leading Scientific Schools [NSh-7065.2010.3]
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In search of a synthesis of o-quinone-tetrathiafulvalene-o-quinone triads a novel facile route was developed. Sodium tetrathiooxalate was for the first time used as a synthon in functionalized TTF preparation. The main purpose of this work was to construct an organic compound, which on the one hand possesses a redox-amphotericity, and on the other hand can act as a bridging ligand in construction of linear, 2D and 3D assemblies. Properties of new acceptor donor acceptor ligand in respect to application as a building block for the molecular devices have been investigated. (C) 2010 Elsevier Ltd. All rights reserved.
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