4.4 Article

Selective aerobic oxidation of sulfides to sulfoxides catalyzed by coenzyme NAD+ models

Journal

TETRAHEDRON
Volume 66, Issue 46, Pages 8823-8827

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.09.076

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Funding

  1. National Natural Science Foundation of China [20802015, 20772115]

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Coenzyme NAD(+) models can be applied in the photooxygenation of sulfides to sulfoxides as organocatalysts at room temperature. A series of sulfoxides are synthesized easily with this protocol and the possible mechanism is discussed. This procedure provides a reliable approach to the clean production of useful sulfoxides in synthetic chemistry. (C) 2010 Elsevier Ltd. All rights reserved.

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