Journal
TETRAHEDRON
Volume 66, Issue 33, Pages 6340-6348Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.04.003
Keywords
Diels-Alder; Sulfone; Oxidation; Allylation; Cyclolactonisation
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A highly functionalized fragment corresponding to the Northern hemisphere of the briaranes has been synthesized employing a sulfonyl diene Diels-Alder reaction, oxidative desulfonylation, Eschenmoser rearrangement and Keck radical allylation. (C) 2010 Elsevier Ltd. All rights reserved.
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