Journal
TETRAHEDRON
Volume 66, Issue 43, Pages 8377-8382Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.08.078
Keywords
Copper(II) tetrafluoroborate; Nanoporous aluminosilicates; Lewis acid catalyst; Meinwald rearrangement
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Funding
- Engineering and Physical Sciences Research Council
- EPSRC National Mass Spectrometry Service, Swansea University
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Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed. (C) 2010 Elsevier Ltd. All rights reserved.
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