Journal
TETRAHEDRON
Volume 66, Issue 31, Pages 5902-5907Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.05.079
Keywords
Hypervalent; Iodine; Oxidation; Dimethyldioxirane
Categories
Funding
- EPSRC
- Deutsche Forschungsgemeinschaft (DFG)
Ask authors/readers for more resources
The synthesis and application of some new hypervalent iodine compounds bearing chiral and achiral ester motives derived from easily accessible starting materials is presented. The oxidation is carried out using dimethyldioxirane as an oxidant providing the desired compounds in moderate to high yields. A crystal structure analysis for one iodine(V) derivative is investigated. The lambda(5)-iodanes are applied as stoichiometric reagents in the oxidation of thioanisole to phenylmethyl sulfoxide, benzyl alcohol to benzaldehyde, and meso-hydrobenzoine to benzaldehyde, benzyl, and benzoin. (C) 2010 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available