Journal
TETRAHEDRON
Volume 66, Issue 47, Pages 9182-9186Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.09.073
Keywords
Imido; Titanium; Carbodiimide; Urea; Isocyanate; Heterocumulene metathesis
Categories
Funding
- University of Nottingham University College London
- Flexible Foam Research Ltd
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An efficient it synthesis of carbodiimides or ureas from the combination of a titanium imido complex 2 and a range of 12 aryl and aliphatic isocyanates is described Control experiments suggest that carbodimide formation is via heterocumulene metathesis through a transient intermediate eta(2)-ureato-N O metallacycle 8 (C) 2010 Elsevier Ltd All rights reserved
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