Journal
TETRAHEDRON
Volume 66, Issue 21, Pages 3801-3813Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.03.047
Keywords
Lewis-base catalysis; N-heterocyclic carbene; Organocatalysis; Carboxyl transfer; Spiro[pyrrolidine-3,3 '-oxindole]
Categories
Funding
- Royal Society
- EPSRC
- AstraZeneca
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NHC-promoted O- to C-carboxyl transfer of 3-allyl indolyl phenyl carbonates generates 3-allyl-3-phenoxycarbonyl-oxindoles with good catalytic efficiency, which are readily converted into (+/-)-N-benzylcoerulescine and (+/-)-horsfiline. (C) 2010 Elsevier Ltd. All rights reserved.
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