Journal
TETRAHEDRON
Volume 66, Issue 26, Pages 4710-4718Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.04.020
Keywords
MIDA boronates; Iterative cross-coupling; Small molecule synthesis; Alkynes Sonogashira coupling; Diels-Alder
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Funding
- NSF [0747778]
- Howard Hughes Medical Institute
- Arnold and Mabel Beckman Foundation
- Bristol-Myers Squibb
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0747778] Funding Source: National Science Foundation
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Ethynyl N-methyliminodiacetic acid (MIDA) boronate is a very useful building block for small molecule synthesis. This compound can serve as both a bifunctional acetylene equivalent with the capacity for terminus-selective bis-functionalization and a versatile starting material for the preparation of a wide range of other MIDA boronate building blocks. (C) 2010 Elsevier Ltd. All rights reserved.
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