4.4 Article

Iron/copper promoted oxidative homo-coupling reaction of terminal alkynes using air as the oxidant

Journal

TETRAHEDRON
Volume 66, Issue 23, Pages 4029-4031

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.04.017

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Funding

  1. Scientific Research Foundation for the State Education Ministry [107108]

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An inexpensive catalytic system, which used a readily available Fe(acac)(3) and trace quantity of Cu (acac)(2) as the co-catalyst and air as the oxidant for the homo-coupling of terminal alkynes, has been developed. The catalytic system could also apply to the cross-coupling reaction of two different terminal alkynes. (C) 2010 Elsevier Ltd. All rights reserved.

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