Journal
TETRAHEDRON
Volume 66, Issue 6, Pages 1188-1195Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.12.043
Keywords
Palladium; Imidazolium; Double coupling; Dihaloarene
Categories
Funding
- NSF of China [20872129, J0830413]
- Zhejianor University K P. Chao's High Technology Development Foundation
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A simple method for one-pot sequential Heck/Suzuki Coupling reactions of a range of substituted aryl dihalides has been described The Pd(OAc)(2)/imidazolium system catalyzed double coupling reactions proceed Without isolation of the intermediates giving unsymmetrically polysubstituted biphenyls ill good to excel lent yields Further couplings of the resultant products bearing additional C-Cl bonds with substituted arylboronic acids or amines lead to unsymmetrical terphenyls and aminobiphenyl derivatives (C) 2009 Elsevier Ltd All rights reserved
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