Journal
TETRAHEDRON
Volume 66, Issue 10, Pages 1832-1836Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.01.045
Keywords
Electrophilic addition; Trifluoroethanol; Hexafluoroisopropanol; Hydrogen bonds
Categories
Funding
- RFBR [09-03-00666]
- Presidium RAS Program [18P-2009]
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Hexafluoroisopropanol (HFIP) was found to be a powerful electrophilic activator of covalent reagents. Due to this effect the title reaction was shown to proceed under mild conditions in the absence of any Lewis acid catalysts to give the respective products of C-alkylation in good to excellent yields. (C) 2010 Elsevier Ltd. All rights reserved.
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