Journal
TETRAHEDRON
Volume 66, Issue 12, Pages 2119-2122Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.01.081
Keywords
Palladium; N-Heterocyclic carbene; C-S coupling; Sulfide
Categories
Funding
- National Science Council, Taiwan, ROC [NSC97-2113-M002-013-MY3]
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N-Heterocyclic carbenes (NHCs) are known to be useful ligands for palladium-complex catalysis It was found that [(NHC)Pd(PPh3)Cl-2] is an effective pre-catalyst in Pd-catalyzed C-S cross coupling reactions to produce the functionalized sulfides in excellent yields The turn over frequency (TOF) for the coupling of p-CH3C6H4Bi with p-CH3C6H4SH reaches to 6 25 (mol Of product) (mole of catalyst)(-1) h(-1) (C) 2010 Elsevier Ltd All rights reserved
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