4.4 Article

P4S10/dimethicone tandem: efficient reagent for thionation of various aromatic amides and esters

Journal

TETRAHEDRON
Volume 66, Issue 30, Pages 5583-5588

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.05.100

Keywords

Thionation; Dimethicone; Phosphoruspentasulfide; Thioamide; Thioester

Funding

  1. Korean Ministry of Education

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Organosulfur compounds are valuable because of their rich and varied chemistry especially in biological field. We report a new and efficient way for thionation of various aromatic amides and esters using P4S10/dimethicone tandem. The ease of handling and higher yield makes this protocol economical. (C) 2010 Elsevier Ltd. All rights reserved.

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