Journal
TETRAHEDRON
Volume 66, Issue 41, Pages 8160-8168Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.08.045
Keywords
Sesquiterpenes; Aciphyllenes; Limonene; Intramolecular type II carbonyl ene reaction; Enantiospecific synthesis
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Funding
- Council of Scientific and Industrial Research, New Delhi
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Enantiospecific total synthesis of the sesquiterpene aciphyllene and its three epimers have been described starting from the readily available monoterpene (R)-limonene employing an intramolecular type II carbonyl ene reaction as the key step. (C) 2010 Elsevier Ltd. All rights reserved.
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