Journal
TETRAHEDRON
Volume 66, Issue 6, Pages 1220-1227Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.12.030
Keywords
Alkaloids; Pyrrolidines; Nitrones
Categories
Funding
- Spanish Ministry of Science and Education (MEC Madrid, Spain) [CTQ2007-67532-C02-01]
- FEDER Program
- Government of Aragon
- MiUR (Italy)
- Gobjerno de Aragon
- Spanish Ministry of Science and Education (MEC Madrid, Spain) [CTQ2007-67532-C02-01]
- FEDER Program
- Government of Aragon
- MiUR (Italy)
- Gobjerno de Aragon
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Several new polyhydroxylated alkaloids including pyrrolidines with a long side chain and 3-(hydroxymethyl) indolizidines were prepared from a common nitrone easily obtained from Do-arabinose In addition. a total synthesis of hyacinthacine A(2) has been achieved in five steps and 67 7% overall yield starting from the same D-arabino-derived nitrone All synthesized compounds have a common structural feature consisting of a pyrrolidine ring with D-arabino configuration (C) 2009 Elsevier Ltd All rights reserved
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