Journal
TETRAHEDRON
Volume 66, Issue 33, Pages 6647-6655Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.04.131
Keywords
Welwitindolinone; [3+2] Dipolar cycloaddition; Rhodium carbenoid; O-H insertion; Chloronium-ion semi-pinacol
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Funding
- NCI NIH HHS [R01 CA093591, R01 CA093591-01A1] Funding Source: Medline
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Described is the construction of the N-methylwelwitindolinone C core via an efficient strategy that employs a sequential rhodium carbenoid-mediated O-H insertion, Claisen rearrangement and transannular [3+2] nitrone cycloaddition. (C) 2010 Elsevier Ltd. All rights reserved.
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