Journal
TETRAHEDRON
Volume 65, Issue 4, Pages 883-887Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.11.041
Keywords
Cinnamomum cassia; Traditional Chinese Medicine; Geranylphenylacetate glycoside; Cinnacassides; Chiroptical methods; Structure elucidation
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Funding
- Key Project of National Natural Science Foundation [30630072, 30721005]
- Shanghai Municipal Scientific Foundation [06DZ22028]
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Cinnacassides A-E (1-5), five novel glycosides with a unique geranylphenylacetate carbon skeleton, were isolated froth the stem bark of Cinnamomum cassia. Each of the cinnacassides A-D (1-4) possesses one of the four stereoisomers in the aglycone. Their structures were established by extensive spectroscopic analysis and chemical and chiroptical methods. A plausible biosynthetic route to 1-5 was also proposed. (C) 2008 Elsevier Ltd. All rights reserved.
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