Journal
TETRAHEDRON
Volume 65, Issue 9, Pages 1785-1789Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.10.110
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Funding
- NIGMS NIH HHS [R01 GM060578, R01 GM060578-10] Funding Source: Medline
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The addition of nucleophilic methoxyarenes to allenes proceeds at room temperature in dichloromethane with a catalytic amount of phosphite-gold(I) precatalyst and silver additive. The addition is regioselective for the allene terminus, and generates E-allylation products without the need for pre-functionalization of the synthons as organometallics or allyl bromides. Coordinating hereroaromatics and sterically hindered allenes do not participate in the reaction. (C) 2008 Elsevier Ltd. All rights reserved.
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