Journal
TETRAHEDRON
Volume 65, Issue 50, Pages 10485-10494Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.10.006
Keywords
Cyclization; Organocatalysis; Enantioselective catalysis; Cyclopentanes; Cyclohexanes; pi-Allylpalladium complexes
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Funding
- Serbian Ministry of Science [142021]
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A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.
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