Journal
TETRAHEDRON
Volume 65, Issue 26, Pages 4984-4991Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.03.088
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Funding
- DFG [Ga 619/7-1]
- Fonds der Chemischen Industrie
- Alexander von Humboldt-Stiftung
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A system with coupled catalytic cycles is described that allows radical reduction by catalyzed hydrogen atom transfer (CHAT) from transition metal hydrides. These intermediates are generated through H-2 activation. Radical generation is carried out by titanocene catalyzed electron transfer to epoxides. The reaction provides a novel entry into the atom-economical reduction of radicals that has long been considered as a critical issue for the industrial application of radical chemistry. (C) 2009 Elsevier Ltd. All rights reserved.
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