Journal
TETRAHEDRON
Volume 65, Issue 13, Pages 2649-2654Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.01.096
Keywords
Tricyclo[5.3.1.0]1(+)S]undecane; (S)-Campholenaldehyde; Enantiospecific synthesis; RCM reaction; Diquinanes; Illicinones
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Funding
- Department of Science and Technology, New Delhi
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Enantiospecific synthesis of the tricyclic core structure present in the biologically active natural products tricycloillicinone, ialibinones, and takaneones, starting from the readily available campholenaldehyde employing a transannular RCM reaction as the key step, has been accomplished. (c) 2009 Elsevier Ltd. All rights reserved.
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