4.4 Article

Gold(I)-catalyzed hydration of allenes

Journal

TETRAHEDRON
Volume 65, Issue 9, Pages 1794-1798

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.10.113

Keywords

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Funding

  1. NSF [CHE-0555425]
  2. NIH [GM080422]
  3. Johnson Johnson

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A gold(I) N-heterocyclic carbene complex catalyzes the intermolecular hydration of allenes to form allylic alcohols in modest yield with selective delivery of water to the terminal carbon atoms of the allenyl moiety. (C) 2009 Elsevier Ltd. All rights reserved.

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