Journal
TETRAHEDRON
Volume 64, Issue 51, Pages 11745-11750Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.09.095
Keywords
Ruthenium; Allylic alcohol; Isomerization
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Funding
- University of Rennes
- UMR [6226]
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The catalytic activity of the ruthenium(II) complex [RuCp(CH3CN)(3)][PF6] 1 in the transposition of allylic alcohols into carbonyl Compounds, in acetonitrile, is reported. This catalyst has proven to be able to catalyze the transformation of poorly reactive and/or functionalized substrates under smooth conditions. (C) 2008 Published by Elsevier Ltd.
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