Journal
TETRAHEDRON
Volume 64, Issue 44, Pages 10258-10266Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.08.007
Keywords
OPV; Resorcinarene; Dendrimers; Cyclic voltammetry; Electrochromism
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Dendrimers with resorcinarene core and Tr-conjugated dendron branches with 16 and 32 stilbene groups have been synthesized and characterized by H-1 and C-13 NMR, FTIR, UV-vis, fluorescence spectroscopy, MALDI-TOF, electrospray or FAB(+) mass spectrometry, and elemental analysis. Homogeneous thin films of resorcinarene-dendrimers deposited on quartz, glass or ITO substrates were prepared by spin-coating. All the materials showed absorption in the UV region in both chloroform solutions and thin films. The band gap energies (Eg) determined from both UV-vis spectroscopy and voltammetry were in the semi-conducting range. A slight decrease in the E. values was observed when passing from the first generation of dendrimers to the second one, which can be attributed to an increase in the pi-conjugated system. The fluorescence quantum yield of the molecules in solution was low and practically null in the solid state. Nevertheless, a very interesting behavior was observed in the reductive voltammetric cycle, where electrochromism from transparent to blue forms occurred in the film by n-doping Process; property that makes these materials suitable for the development of electrochromism devices such as smart windows. Crown Copyright (c) 2008 Published by Elsevier Ltd. All rights reserved.
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