Journal
TETRAHEDRON
Volume 64, Issue 40, Pages 9408-9412Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.07.092
Keywords
rhodium; asymmetric catalysis; reductive aldol reaction; Felkin-Anh; bisoxazoline
Categories
Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [460:18065011]
- Japan Society for the Promotion of Science [18350049]
- G-COE in Chemistry
- Grants-in-Aid for Scientific Research [18350049] Funding Source: KAKEN
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The catalytic reductive aldol coupling of 2-phenylpropionaldehyde and acrylate derivatives with rhodium-bisoxazolinyl catalysts resulted in high Felkin-Anh selectivity (beta,gamma-syn) up to 98% accompanied by alpha,beta-anti diastereoselectivity and high enantiomeric excesses up to 99%. (C) 2008 Elsevier Ltd. All rights reserved.
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