Journal
TETRAHEDRON
Volume 64, Issue 2, Pages 328-338Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.10.105
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Palladium-catalyzed Suzuki-Miyaura Coupling of N-benzenesulfonyl-3,4-dibromopyrrole with a variety of arylboronic acids gave the corresponding 3,4-diarylpyrroles in high yields. The 3,4-differentially arylated pyrroles could also be prepared by stepwise cross-coupling approach. The total syntheses of lamellarins O, P, Q, and R have been achieved by using the cross-coupling and the directed lithiation as key reactions. (c) 2007 Elsevier Ltd. All rights reserved.
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