Journal
TETRAHEDRON
Volume 64, Issue 26, Pages 6051-6059Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.12.060
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The ruthenium-catalyzed direct ortho-arylation reactions of 2-phenylpyridine and 2-aryloxazolines have been successfully expanded to the direct aryl-heteroaryl coupling reactions using heteroaryl bromides. The reaction mechanism involving the Ru-II/Ru-IV intermediates is proposed from the results of the stoichiometric reaction of a divalent ruthenacycle complex of 2-phenylpyridine with bromobenzene. (C) 2008 Elsevier Ltd. All rights reserved.
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